Zeitschriften
Zeitschriften
Chlorodefluorination Induced by Gallium-Based Lewis Acids
K. Tölke, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. (2024) e202403226.
DOI: 10.1002/chem.202403226
Halogen Bonding in N-Alkyl-bromo-/iodo-pyridinium Salts and its Application in Chromatography
P. Wendt, J. Bader, P. L. Waltersmann, J.-H. Schröder, M. Keßler, H.-G Stammler, B. Neumann, A. Delp, F. Paesler, M. Schulte, B. Hoge, Chem. Eur. J. (2024) e202403062.
DOI: 10.1002/chem.202403062
First Main-Group Element Lewis Acid Thionyl Chloride Adduct and its Chemistry
K. Tölke, S. Porath, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. (2024) e202408741; Angew. Chem. Int. Ed. (2024) e202408741.
DOI: 10.1002/ange.202408741; DOI: 10.1002/anie.202408741 (Int. Ed.)
Water-Stable Lewis Superacids as Precursors for (Pseudo)halogenogallate and -indate Salts
K. Tölke, S. Porath, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. (2024) e202400191.
DOI: 10.1002/ejic.202400191
Water Adducts of the Lewis Superacids: Tris(pentafluoroethyl)gallane and -indane
K. Tölke, S. Porath, Y. V. Vishnevskiy, B. Neumann, H.-G. Stammler, N. W. Mitzel, B. Hoge, Eur. J. Inorg. Chem. 27, (2024) e202300759.
DOI: 10.1002/ejic.202300759
Gallate and Indate Salts with Unsaturated Electron Withdrawing Groups
S. Porath, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. 27, (2024) e202300642.
DOI: 10.1002/ejic.202300642
Ice nucleation in aqueous solutions of short- and long-chain poly(vinyl alcohol) studied with a droplet microfluidics setup
L. Eickhoff, M. Keßler, C. Stubbs, J. Derksen, M. Viefhues, D. Anselmetti, M. I. Gibson, B. Hoge, T. Koop, J. Chem. Phys. 158, (2023) 154504.
DOI: 10.1063/5.0136192
Triorganylphosphoranides: Realization of an Unusual Structural Motif Utilizing Electron Withdrawing Pentafluoroethyl Groups
M. Keßler, M. Kapiza, H.-G. Stammler, B. Neumann, G.-V. Röschenthaler, B. Hoge, ChemPlusChem 88, (2023) e202200436.
DOI: 10.1002/cplu.202200436
News in ChemistryViews:
Synthesis and Characterization of Tetrakis(pentafluoroethyl)indate Salts
S. Porath, M. Keßler, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 29, (2023) e202203278.
DOI: 10.1002/chem.202203278
Synthesis and characterization of tetrafluorophenyl phosphonic acid functionalized polyacrylates as potential proton conducting materials in fuel cells
C. Alter, R. F. Weitkamp, B. Hoge, J. Appl. Polym. Sci. 140(3) (2022) e53313.
DOI: 10.1002/app.53313
Free Difluorobis(pentafluoroethyl)phosphoranide Ion and Its Ligand Properties
M. Keßler, L. Hartmann, H.-G. Stammler, B. Neumann, G.-V. Röschenthaler, B. Hoge, Inorg. Chem. 61 (2022) 10833–10843.
DOI: 10.1021/acs.inorgchem.2c01143
News in ChemistryViews: + Hot Paper
Synthesis, Reactivity and Structural Properties of Trifluoromethylphosphoranides
O. O. Shyshkov, A. A. Kolomeitsev, B. Hoge, E. Lork, A. Haupt, M. Keßler, G.-V. Röschenthaler, Chem. Eur. J. 28 (2022) e202104308.
DOI: 10.1002/chem.202104308
Hot Paper + Frontispiece:
Oxidative Additions of C−F Bonds to the Silanide Anion [Si(C2F5)3]−
N. Tiessen, M. Keßler, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 134 (2022) e202116468; Angew. Chem. Int. Ed. 61 (2022) e202116468.
DOI: 10.1002/ange.202116468;DOI: 10.1002/anie.202116468 (Int. Ed.); Frontispiece
News in ChemistryViews:
Difluorobis(pentafluoroethyl)phosphoranide: A Promising Building Block for Phosphoranidometal Complexes
M. Keßler, H.-G. Stammler, B. Neumann, G.-V. Röschenthaler, B. Hoge, Inorg. Chem. 60 (2021) 16466–16473.
DOI: 10.1021/acs.inorgchem.1c02307
Salts of Tris(pentafluoroethyl)silylchalcogenolates [Si(C2F5)3E]− with E = S, Se, and Te: Synthesis, Structure, and Reactivity
N. Tiessen, N. Schwarze, H.-G. Stammler, B. Neumann, B. Hoge, Inorg. Chem. 60 (2021) 15112–15117.
DOI: 10.1021/acs.inorgchem.1c02476
Cover Feature:
Tris(pentafluoroethyl)silanol Derivatives and the Lewis Amphoteric Tris(pentafluoroethyl)silanolate Anion, [Si(C2F5)3O]−
N. Tiessen, N. Schwarze, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 27 (2021) 11041–11044.
DOI: 10.1002/chem.202101845
Frontispiece:
Phosphorus-containing Superbases: Recent Progress in the Chemistry of Electron-abundant Phosphines and Phosphazenes
R. F. Weitkamp, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 27 (2021) 10807–10825.
DOI: 10.1002/chem.202101065; Frontispiece
Frontispiece:
The Influence of Weakly Coordinating Cations on the O−H⋅⋅⋅O− Hydrogen Bond of Silanol‐Silanolate Anions
R. F. Weitkamp, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 27 (2021) 915–920.
DOI: 10.1002/chem.202004236; Frontispiece
VIP + Front Cover:
Structural Characterization of Hydro-, Chloro- and Fluoroorganylsilanes with Substituents of Varying Electron Withdrawing Character
M. Keßler, S. Porath, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. (2021) 907–913.
DOI: 10.1002/ejic.202001065; Cover
Hot Paper + Front Cover:
Nachweis des Lewis-amphoteren Charakters von Tris(pentafluorethyl)silanid, [Si(C2F5)3]−
N. Tiessen, M. Keßler, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 133 (2021) 12231–12238; Angew. Chem. Int. Ed. 60 (2021) 12124–12131.
DOI: 10.1002/ange.202016455; DOI: 10.1002/anie.202016455 (Int. Ed.); Front Cover
Hot Paper + Cover Feature:
Non-coordinated and Hydrogen Bonded Phenolate Anions as One-Electron Reducing Agents
R. F. Weitkamp, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 27 (2021) 6465–6478.
DOI: 10.1002/chem.202005123; Cover
Cover Feature:
Ishikawa’s Reagent – a Valuable Source for Fluoroorganic Iminium Salts
M. Keßler, B. Neumann, H.-G. Stammler, B. Hoge, Z. Anorg. Allg. Chem. 647 (2021) 225–230.
DOI: 10.1002/zaac.202000198; Cover
Hot Paper + Cover Feature:
Non-Coordinated Phenolate Anions and Their Application in SF6 Activation
R. F. Weitkamp, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 27 (2021) 6460–6464.
DOI: 10.1002/chem.202003504; Cover
Hot Paper + Cover Feature:
Synthesis and Characterization of Tetrakis(pentafluoroethyl)aluminate
N. Tiessen, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 26 (2020) 13611–13614.
DOI: 10.1002/chem.202000668; Back Cover
Autoren-Profil:
Unter Druck entstehen Diamanten (Berthold Hoge)
B. Hoge, Angew. Chem. 132 (2020) 20924; Angew. Chem. Int. Ed. 59 (2020), 20740.
DOI: 10.1002/ange.202008186; DOI: 10.1002/anie.202008186 (Int. Ed.)
Fluorotrimethyl[(Z)-pentafluoropropen-1-yl]phosphorane: Structure, Bonding, and Reactivity
M. Keßler, B. Neumann, H.-G. Stammler, B. Hoge, Z. Anorg. Allg. Chem. 646 (2020) 784–789.
DOI: 10.1002/zaac.202000047
Synthese und Reaktivität der ersten isolierten wasserstoffverbrückten Silanol-Silanolat-Anionen
R. Weitkamp, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 132 (2020) 5536–5541; Angew. Chem. Int. Ed. 59 (2020) 5494–5499.
DOI: 10.1002/ange.201914339; DOI: 10.1002/anie.201914339 (Int. Ed.)
VIP + Back Cover:
Generierung und Anwendung des Hydroxid-Trihydrat-Anions, [OH(OH2)3]−, stabilisiert durch ein schwach koordinierendes Kation
R. Weitkamp, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 131 (2019) 14775–14780; Angew. Chem. Int. Ed. 58 (2019) 14633–14638.
DOI: 10.1002/ange.201908589; DOI: 10.1002/anie.201908589 (Int. Ed.); Back Cover
Phosphido-Bridged Di- and Trinuclear Palladium Complexes from Electron-Poor Phosphanes R2PH (R = C2F5, C6F5, (CF3)2C6H3)
J. Bader, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. (2019) 3904–3912.
DOI: 10.1002/ejic.201900728
Cover Image:
Synthesis and characterization of a novel highly phosphonated water-insoluble polymer
C. Alter, B. Neumann, H.-G. Stammler, B. Hoge, J. Appl. Polym. Sci. (2019) 48235.
DOI: 10.1002/app.48235; Cover
VIP + Cover + Cover Profile:
Synthesis and Reactivity of Tris(pentafluoroethyl)gallium Compounds
M. Niemann, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. (2019) 3462–3475.
DOI: 10.1002/ejic.201900486; Cover; Cover Profile
Synthese, Eigenschaften und Anwendung von Tetrakis(pentafluorethyl)gallat, [Ga(C2F5)4]−
M. Niemann, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 131 (2019) 9033–9038; Angew. Chem. Int. Ed. 58 (2019) 8938–8942.
DOI: 10.1002/ange.201904197; DOI: 10.1002/anie.201904197 (Int. Ed.)
Synthesis and characterization of a novel difluoromethylene phosphonic acid functionalized polymer
C. Alter, B. Hoge, J. Appl. Polym. Sci. 135 (2018) 46765.
DOI: 10.1002/app.46765
Coordination Chemistry of the Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2F5)3]−
J. Klösener, M. Wiesemann, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. (2018) 3971–3977.
DOI: 10.1002/ejic.201800796
Hypercoordinated Fluoro(pentafluoroethyl)stannanes and -stannates
J. Klösener, M. Wiesemann, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. (2018) 3960–3970.
DOI: 10.1002/ejic.201800795
Reviews Showcase:
Pentafluoroethylated Compounds of Silicon, Germanium and Tin
M. Wiesemann, B. Hoge, Chem. Eur. J. 24 (2018) 16457–16471.
DOI: 10.1002/chem.201801292
Hot Paper + Cover Feature:
Activation of CH3CN with (C2F5)3PF2 and amines
J. Bader, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 24 (2018) 6975–6982.
DOI: 10.1002/chem.201800682; Inside Cover
Hot Paper:
Synthesis and Reactivity of Donor-Stabilized Bis(pentafluoroethyl)stannylene [Sn(C2F5)2(D)n] (D=THF, DMAP, PMe3, [Sn(C2F5)3]−)
J. Klösener, M. Wiesemann, M. Niemann, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 24 (2018) 4412–4422.
DOI: 10.1002/chem.201705770
The Dynamic Equilibrium of Hexakis(pentafluoroethyl)distannane Adducts [XSn(C2F5)3{Sn(C2F5)3}]− (X=Cl, Br, I, Sn(C2F5)3)
M. Wiesemann, J. Klösener, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 24 (2018) 4336–4342.
DOI: 10.1002/chem.201705069
VIP:
Syntheses of stable salts containing the hydridophosphate anion [P(C2F5)3F2H]−
J. Bader, N. Ignat'ev, B. Hoge, Eur. J. Inorg. Chem. 2018 (2018) 861–866.
DOI: 10.1002/ejic.201701375
Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids
C. Alter, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. 2018 (2018) 867–875.
DOI: 10.1002/ejic.201701402
Tris(pentafluoroethyl)stannane: Tin Hydride Chemistry with an Electron-Deficient Stannane
M. Wiesemann, M. Niemann, J. Klösener, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 24 (2018) 2699–2708.
DOI: 10.1002/chem.201705068
Metal-free dehydrogenation of tri- and diethylamine with (C2F5)3PF2
J. Bader, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, J. Fluorine Chem. 207 (2018) 12–17.
DOI: 10.1016/j.jfluchem.2017.12.015
Hot Paper + Cover Feature:
On Pentakis(pentafluoroethyl)stannate, [Sn(C2F5)5]−, and the Gas-Free Generation of Pentafluoroethyllithium, LiC2F5
M. Wiesemann, J. Klösener, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 24 (2018) 1838–1843.
DOI: 10.1002/chem.201704807; Inside Cover
Hot Paper + Cover Feature:
The Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2F5)3]− – Synthesis and Reactivity
M. Wiesemann, J. Klösener, M. Niemann, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 23 (2017) 14476–14484.
DOI: 10.1002/chem.201702855; Inside Cover
VIP + Front Cover + Cover Profile:
Solid-State Structure of a Bromo(difluoromethylenephosphonato)cuprate - a Key Intermediate for the Synthesis of α,α-Difluoromethylenephosphonates
C. Alter, B. Neumann, H.-G. Stammler, L. Weber, B. Hoge, Eur. J. Inorg. Chem. 2017 (2017) 3489–3493.
DOI: 10.1002/ejic.201700526; Cover; Cover Profile
Perfluoroalkylated Main-Group Element Lewis Acids as Catalysts in Transfer Hydrogenation
J. Bader, A. F. G. Maier, J. Paradies, B. Hoge, Eur. J. Inorg. Chem. 2017 (2017) 3053–3056.
DOI: 10.1002/ejic.201700524
Synthesis of Mono-, Bis- and Tris(pentafluoroethyl)tin Derivatives, (C2F5)4–nSnXn (X=Ph, Me, Cl, Br, Cp; n = 1–3)
J. Klösener, M. Wiesemann, M. Niemann, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 23 (2017) 8295–8303.
DOI: 10.1002/chem.201701270
Feature:
Synthesis and Characterization of Tetrakis(pentafluoroethyl)germane
S. Pelzer, B. Neumann, H.-G. Stammler, N. Ignat'ev, R. Eujen, B. Hoge, Synthesis 49 (2017) 2389–2393.
DOI: 10.1055/s-0036-1589005
Hot Paper:
Tris(pentafluoroethyl)germane: Deprotonation and Hydrogermylation Reactions
S. Pelzer, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 23 (2017) 12233–12242.
DOI: 10.1002/chem.201700634
Hot Paper + Back Cover:
Pentafluoroethyl Bismuth Compounds
S. Solyntjes, J. Bader, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 23 (2017) 1557–1567.
DOI: 10.1002/chem.201604910; Back Cover
Bismuth Perfluoroalkylphosphinates: New Catalysts for Application in Organic Syntheses
S. Solyntjes, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 23 (2017) 1568–1575.
DOI: 10.1002/chem.201604914
VIP + Inside Back Cover:
Das Tris(pentafluorethyl)silanid-Anion
N. Schwarze, S. Steinhauer, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 128 (2016) 16390–16394; Angew. Chem. Int. Ed. 55 (2016) 16156–16160.
DOI: 10.1002/ange.201609096; DOI: 10.1002/anie.201609096 (Int. Ed.); Cover
Nukleophile Übertragungsreaktionen der [Si(C2F5)3]−-Einheit
N. Schwarze, S. Steinhauer, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 128 (2016) 16395–16398; Angew. Chem. Int. Ed. 55 (2016) 16161–16164.
DOI: 10.1002/ange.201609575; DOI: 10.1002/anie.201609575 (Int. Ed.)
Pentafluorethylkieselsäuren
N. Schwarze, S. Steinhauer, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 128 (2016) 15756–15759; Angew. Chem. Int. Ed. 55 (2016) 15528–15530.
DOI: 10.1002/ange.201609097; DOI: 10.1002/anie.201609097 (Int. Ed.)
Synthesis of Functional Bis(pentafluoroethyl)silanes (C2F5)2SiX2,
with X = H, F, Cl, Br, OPh, O2CCF3
N. Schwarze, B. Kurscheid, S. Steinhauer, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 22 (2016) 17460–17467.
DOI: 10.1002/chem.201603442
Hot Paper:
Hypervalent Pentafluoroethylgermanium Compounds, [(C2F5)nGeX5–n]− and [(C2F5)3GeF3]2- (X = F, Cl; n = 2–5)
S. Pelzer, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 22 (2016) 16460–16466.
DOI: 10.1002/chem.201602859
Cover + Cover Profile:
Novel Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium salts
S. Solyntjes, B. Neumann, H.-G. Stammler, N. Ignatiev, B. Hoge, Eur. J. Inorg. Chem. (2016) 3999–4010.
DOI: 10.1002/ejic.201600539; Cover; Cover Profile
Das Bis(pentafluorethyl)germylen-Trimethylphosphan-Addukt, (C2F5)2Ge·PMe3 – Charakterisierung, Ligandeigenschaften und Reaktivität
S. Pelzer, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Angew. Chem. 128 (2016) 6192–6197; Angew. Chem. Int. Ed. 55 (2016) 6088–6092.
DOI: 10.1002/ange.201601468; DOI: 10.1002/anie.201601468 (Int. Ed.)
Hot Paper:
Synthesis of Bis(pentafluoroethyl)germanes
S. Pelzer, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 22 (2016) 4758–4763.
DOI: 10.1002/chem.201505084
Hot Paper + Inside Back Cover:
Synthesis of Tris(pentafluoroethyl)germanes
S. Pelzer, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 22 (2016) 3327–3332.
DOI: 10.1002/chem.201504626; Inside Back Cover
Hot Paper:
Coordination Properties of Perfluoroethyl- and Perfluorophenyl-Substituted Phosphonous acids, RfP(OH)2
N. Allefeld, B. Kurscheid, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 21 (2015) 13666–13675.
DOI: 10.1002/chem.201501984
Transition Metal Complexes of Phosphinous Acids Featuring a Quasichelating Unit: Synthesis, Characterization, and Hetero-bimetallic Complexes
N. Allefeld, J. Bader, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Inorg. Chem. 54 (2015) 7945–7952.
DOI: 10.1021/acs.inorgchem.5b01038
Hot Paper + Inside Cover:
Functionalized Pentafluoroethylphosphanes
N. Allefeld, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 21 (2015) 12326–12336.
DOI: 10.1002/chem.201501733; Inside Cover
Correction: Pentafluoroethyl-substituted α-Silanes: Model Compounds for New Insights
B. Waerder, S. Steinhauer, C. G. Reuter, J. Bader, B. Neumann, H.-G. Stammler, Y. V. Vishnevskiy, B. Hoge, N. W. Mitzel, Dalton Trans. 44 (2015) 14540.
DOI: 10.1039/C5DT90132D
Pentafluoroethyl-substituted α-Silanes: Model Compounds for New Insights
B. Waerder, S. Steinhauer, J. Bader, B. Neumann, H.-G. Stammler, Y. V. Vishnevskiy, B. Hoge, N. W. Mitzel, Dalton Trans. 44 (2015) 13347–13358.
DOI: 10.1039/C5DT02010G
Recent Progress in Perfluoroalkyl-Phosphorus Chemistry
N. V. Ignat'ev, J. Bader, K. Koppe, B. Hoge, H. Willner, J. Fluorine Chem., 171 (2015) 36–45.
DOI: 10.1016/j.jfluchem.2014.10.007
NHC→SiCl4: An Ambivalent Carbene Transfer Reagent
T. Böttcher, S. Steinhauer, L. C. Lewis-Alleyne, B. Neumann, H.-G. Stammler, B. S. Bassil, G.-V. Röschenthaler, B. Hoge, Chem. Eur. J., 21 (2015) 893–899.
DOI: 10.1002/chem.201404628
Festkörperstruktur eines Li⁄F-Carbenoids: Pentafluorethyllithium
B. Waerder, S. Steinhauer, B. Neumann, H.-G. Stammler, A. Mix, Y. V. Vishnevskiy, B. Hoge, N. W. Mitzel, Angew. Chem., 126 (2014), 11824–11828; Angew. Chem. Int. Ed., 53 (2014) 11640–11644.
DOI: 10.1002/ange.201406564; DOI: 10.1002/anie.201406564 (Int. Ed.)
Synthese von Chlorosilikaten
S. Steinhauer, T. Böttcher, N. Schwarze, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem., 126 (2014), 13485–13488; Angew. Chem. Int. Ed., 53 (2014), 13269–13272.
DOI: 10.1002/ange.201406311; DOI: 10.1002/anie.201406311 (Int. Ed.)
Synthesis of Functional Phosphates [P(C2F5)3F2X]− from the Phosphorane Adduct [P(C2F5)3F2(dmap)]
J. Bader, N. Ignat'ev, B. Hoge, Inorg. Chem., 53 (2014) 7547–7553.
DOI: 10.1021/ic500857b
Cover + Cover Profile:
Synthesis of Unsymmetrically Substituted Phosphane Oxides (R1R2P(O)H) and Phosphinous Acids (R1R2POH)
N. Allefeld, M. Grasse, N. Ignat'ev, B. Hoge, Chem. Eur. J., 20 (2014) 8615–8620.
DOI: 10.1002/chem.201402425; Cover; Cover Profile
Inside Back Cover:
Pentacoordinate silicon(IV): cationic, anionic and neutral complexes derived from the reaction of NHC→SiCl4 with highly Lewis acidic (C2F5)2SiH2
T. Böttcher, S. Steinhauer, B. Neumann, H.-G. Stammler, G.-V. Röschenthaler, B. Hoge, Chem. Commun., 50 (2014) 6204–6206.
DOI: 10.1039/C4CC02583K; Inside Back Cover
Back Cover:
Synthesis and Reactivity of New Functionalized Perfluoroalkylfluorophosphates
N. Allefeld, B. Neumann, H.-G. Stammler, G.-V. Röschenthaler, N. Ignat'ev, B Hoge, Chem. Eur. J., 20 (2014) 7736–7745.
DOI: 10.1002/chem.201402421; Back Cover
VIP:
Synthese von Tris- und Tetrakis(pentafluorethyl)silanen
S. Steinhauer, J. Bader, H.-G. Stammler, N. Ignat'ev, B. Hoge, Angew. Chem., 126 (2014) 5307–5310; Angew. Chem. Int. Ed., 53 (2014) 5206–5209.
DOI: 10.1002/ange.201400291; DOI: 10.1002/anie.201400291 (Int. Ed.)
Carbene complexes of phosphorus(V) fluorides substituted with perfluoroalkyl-groups synthesized by oxidative addition. Cleavage of the complexes reveals a new synthetic protocol for ionic liquids
T. Böttcher, S. Steinhauer, N. Allefeld, B. Hoge, B. Neumann, H.-G. Stammler, B. S. Bassil, M. Winter, N. W. Mitzel, G.-V. Röschenthaler, Dalton Trans., 43 (2014), 2979–2987.
DOI: 10.1039/C3DT53043D
Synthesis of Five- and Six-coordinated Tris(pentafluoroethyl)fluorosilicates
S. Steinhauer, B. Hoge, B. Neumann, H.-G. Stammler, N. Ignat'ev, Angew. Chem., 126 (2014), 573–575; Angew. Chem. Int. Ed., 53 (2014), 562–564.
DOI: 10.1002/ange.201308059; DOI: 10.1002/anie.201308059 (Int. Ed.)
Functionalized Bis(pentafluoroethyl)phosphanes: Improved Syntheses and Molecular Structures in the Gas Phase
A. V. Zakharov, Y. V. Vishnevskiy, N. Allefeld, J. Bader, B. Kurscheid, S. Steinhauer, B. Hoge, B. Neumann, H.-G. Stammler, R. J. F. Berger, N. W. Mitzel, Eur. J. Inorg. Chem. (2013) 3392–3404.
DOI: 10.1002/ejic.201300364
Synthesis of a water stable 2,4-bis(trifluoromethyl)phenyl substituted phosphonous acid palladium complex and its catalytic activity in cross-coupling reactions
B. Kurscheid, H.-G. Stammler, B. Neumann, B. Hoge, Z. Anorg. Allg. Chem., 638 (2012) 534–542.
DOI: 10.1002/zaac.201100344
Air stable and catalytically active phosphinous acid transition metal complexes
B. Kurscheid, L. Belkoura, B. Hoge, Organometallics, 31 (2012) 1329–1334.
DOI: 10.1021/om200697u
Investigations of the tautomeric equilibria between phosphane oxides and their corresponding phosphinous acids bearing electron-withdrawing perfluoroaryl groups
B. Kurscheid, W. Wiebe, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. (2011) 5523–5529.
DOI: 10.1002/ejic.201100984
Air stable platinum and palladium complexes featuring bis[2,4-bis(trifluoromethyl)-phenyl]phosphinous acid ligands
B. Kurscheid, H.-G. Stammler, B. Neumann, B. Hoge, Chem. Eur. J., 17 (2011) 14935–14941.
DOI: 10.1002/chem.201102347
First Solid State Structures of Real Diorganyl Phosphinous Acids R2POH (R = CF3, C2F5)
J. Bader, R. J. F. Berger, H.-G. Stammler, N. W. Mitzel, B. Hoge, Chem. Eur. J., 17 (2011) 13420–13423.
DOI: 10.1002/chem.201102370
Chlorobis(pentafluoroethyl)phosphane: Improved Synthesis and Molecular Structure in the Gas Phase
S. A. Hayes, R. J. F. Berger, N. W. Mitzel, J. Bader, B. Hoge, Chem. Eur. J., 17 (2011) 3968–3976.
DOI: 10.1002/chem.201003048
Molecular structure of tris(pentafluoroethyl)phosphane P(C2F5)3
S. A. Hayes, R. J. F. Berger, B. Neumann, N. W. Mitzel, J. Bader, B. Hoge, Dalton Trans., 39 (2010) 5630–5636.
DOI: 10.1039/c001310b
On the XeF+/H2O System: Synthesis and Characterization of the Xenon(II) Oxide Fluoride Cation, FXeOXeFXeF+
M. Gerken, M. D. Moran, H. P. A. Mercier, B. E. Pointner, G. J. Schrobilgen, B. Hoge, K. O. Christe, J. A. Boatz, J. Am. Chem. Soc., 131 (2009) 13474–13489.
DOI: 10.1021/ja905060v
Fluorinated Dithieno[3,2-b:2’,3’-d]phospholes with Highly Stabilized LUMO Levels
Y. Ren, Y. Dienes, S. Hettel, M. Parvez, B. Hoge, T. Baumgartner, Organometallics, 28 (2009) 734–740.
DOI: 10.1021/om800874d
The Bis(pentafluoroethyl)phosphinous Acid, (C2F5)2POH
B. Hoge, J. Bader, H. Beckers, Y. S. Kim, R. Eujen, H. Willner, N. Ignatiev, Chem. Eur. J., 15 (2009) 3567–3576.
DOI: 10.1002/chem.200801837
The influence of electron withdrawing groups on the chemistry of phosphorus: Tautomerization of novel bis(s-triazinyl)phosphanes
B. Hoge, W. Wiebe, Angew. Chem., 120 (2008) 8236–8239; Angew. Chem. Int. Ed., 47 (2008) 8116–8119.
DOI: 10.1002/ange.200802943; DOI: 10.1002/anie.200802943 (Int. Ed.)
Tetrakis[2,4-bis(trifluoromethyl)phenyl]diphosphoxane - An Anhydride of a Phosphinous Acid
B. Hoge, B. Kurscheid, Angew. Chem., 120 (2008) 6920–6922; Angew. Chem. Int. Ed., 47 (2008) 6814–6816.
DOI: 10.1002/ange.200801025; DOI: 10.1002/anie.200801025 (Int. Ed.)
Convenient Access to Trifluoromethanol
K.O. Christe, J. Hegge, B. Hoge, R. Haiges, Angew. Chem., 119 (2007) 6267–6270; Angew. Chem. Int. Ed., 46 (2007) 6155–6158.
DOI: 10.1002/ange.200701823; DOI: 10.1002/anie.200701823
A Convenient, Selective Synthesis of Bis[2,4-bis(trifluoromethyl)phenyl]phosphane Derivatives Starting from 1,3-Bis(trifluoromethyl)benzene
B. Hoge, B. Kurscheid, S. Peuker, W. Tyrra, H. T. M. Fischer, Z. Anorg. Allg. Chem., 633 (2007) 1679–1685.
DOI: 10.1002/zaac.200700140
A Qualitative Scale for the Electron Withdrawing Effect of Substituted Phenyl Groups and Heterocycles
B. Hoge, J. Bader, J. Fluorine Chem., 128 (2007) 857–861.
DOI:10.1016/j.jfluchem.2007.04.007
Synthesis of a Functional C2 Symmetrical Bidentate Diphenylphosphonite DIOP Derivative and its Conversion into the Corresponding π Acidic Bis(pentafluorophenyl) and Bis(p-tetrafluoropyridyl) Derivatives
B. Hoge, P. Panne, Chem. Eur. J., 12 (2006) 9025–9035.
DOI: 10.1002/chem.200600260
Synthesis of the First Chiral Bidentate Bis(trifluoromethyl)phosphane Ligand via the Stabilization of the Bis(trifluoromethyl)phosphanide Anion in the Presence of Acetone
B. Hoge, C. Thösen, Chem. Eur. J., 12 (2006) 9019–9024.
DOI: 10.1002/chem.200600259
Conference Report: Transatlantic Frontiers of Chemistry
A. Herrmann, B. Hoge, W. Maison, Nachr. Chem., 54 (2006) 1258–1260.
The Bis(trifluoromethyl)phosphinous Acid, (CF3)2P-O-H: An Example of a Thermally Stable Phosphinous Acid-Synthesis, Gas-Phase Structure and Rotational Isomers
B. Hoge, P. Garcia, H. Willner, H. Oberhammer, Chem. Eur. J., 12 (2006) 3567–3574.
DOI: 10.1002/chem.200501066
Silver compounds in synthetic chemistry Part 4. 4-Tetrafluoropyridyl silver(I), AgC5F4N in redox transmetallations-possibilities and limitations in reactions with group 15 elements
W. Tyrra, S. Aboulkacem, B. Hoge, W. Wiebe, I. Pantenburg, J. Fluorine Chem., 127 (2006) 213–217.
DOI:10.1016/j.jfluchem.2005.10.009
How Trimethyl(trifluoromethyl)silane Reacts with Itself in the Presence of Naked Fluoride - A One-Pot Synthesis of Bis([15]crown-5)cesium 1,1,1,3,5,5,5-Heptafluoro-2,4-bis(trifluoromethyl)pentenide
W. Tyrra, M. M. Kremlev, D. Naumann, H. Scherer, H. Schmidt, B. Hoge, I. Pantenburg, Y. L. Yagupolskii, Chem. Eur. J., 11 (2005) 6514–6518.
DOI: 10.1002/chem.200500799
Trendbericht 2004, Anorganische Chemie, Hauptgruppenelemente
H.-J. Himmel, B. Hoge, Nachr. Chem., 53 (2005) 225–235.
Stable Phosphinous Acids
B. Hoge, W. Wiebe, S. Neufeind, S. Hettel, C. Thösen, J. Organomet. Chem., 690 (2005) 2382–2387.
DOI:10.1016/j.jorganchem.2004.09.041
Strategies for the Synthesis of Chiral, Bidentate Bis(perfluoroorganyl)phosphane Ligands
B. Hoge, C. Thösen, T. Herrmann, P. Panne, I. Pantenburg, J. Fluorine Chem., 125 (2004) 831–851.
DOI:10.1016/j.jfluchem.2004.02.012
Preparation and Characterization of the Argentates: [Ag{P(CF3)2}2]−, [Ag{(μ-P(CF3)2)W(CO)5}2]− and [Ag{(μ-P(C6F5)2)W(CO)5}2]− and the the X-ray Crystal Structure of [K(18-crown-6)][Ag{(μ-P(CF3)2)Cr(CO)5}2]
B. Hoge, T. Herrmann, C. Thösen, A. Vij, Inorg. Chem., 43 (2004) 1659–1666.
DOI: 10.1021/ic034936v
Non-cyclic [10-S-5] Sulfuranide Dioxide Salts with Three S-C Bonds: A New Class of Stable Hypervalent Compounds
D. V. Sevenard, A. A. Kolomeitsev, B. Hoge, E. Lork, G.-V. Röschenthaler, J. Am. Chem. Soc., 125 (2003) 12366–12367.
DOI: 10.1021/ja030155h
Preparation and Characterization of [Hg{P(C6F5)2}2], [Hg{(μ-P(C6F5)2)W(CO)5}2] and [Hg{(μ-P(CF3)2)W(CO)5}2] and the X-ray Crystal Structure of [Hg{(μ-P(C6F5)2)W(CO)5}2]·2 DMF
B. Hoge, T. Herrmann, C. Thösen, I. Pantenburg, Inorg. Chem., 42 (2003) 5422–5428.
DOI: 10.1021/ic034448n
Stabilization of the P(CF3)2- and P(C6F5)2- ion by coordination to pentacarbonyl tungsten.
Structures of [18-crown-6-K]P(CF3)2, [18-crown-6-K][W{P(CF3)2}(CO)5] and [18-crown-6-K] [{W(CO)5}2{μ-P(C6F5)2}]·THF
B. Hoge, C. Thösen, T. Herrmann, I. Pantenburg, Inorg. Chem., 42 (2003) 3633–3641.
DOI: 10.1021/ic034165v
Bis(trifluoromethyl)phosphane, Bis(pentafluorophenyl)phosphane and their Pentacarbonyl Tungsten Complexes: Improved Synthesis and an Experimental and Density Functional Study.
B. Hoge, T. Herrmann, C. Thösen, I. Pantenburg, Inorg. Chem., 42 (2003) 3623–3632.
DOI: 10.1021/ic034166n
Vibrational spectra and structures of fluoroalkyl and fluoroaryl compounds of tellurium: Te2(CF3)2, Te2(C6F5)2 and Te(C6F5)2
B. Hoge, D. Naumann, H. Pohl, J. Shamir, J. Raman Spec., 34 (2003) 33–39.
DOI: 10.1002/jrs.936
A new synthesis of trifluoromethanethiolates - characterization and properties of tetramethylammonium, cesium and di(benzo-15-crown-5)cesium trifluoromethanthiolates
W. Tyrra, D. Naumann, B. Hoge, Y. L. Yagupolskii, J. Fluorine Chem., 119 (2003) 101–107.
DOI:10.1016/S0022-1139(02)00276-2
Novel Addition of Diphosphanes to Carbonyl Compounds
B. Hoge, C. Thösen, Phosphorus, Sulfur, Silicon Relat. Elem., 177 (2002) 2151–2152.
DOI: 10.1080/10426500213437
Synthesis and Structure of [Hg{OP(O)CF3(OH)}2(PMe3)3], a Distorted Trigonal Bipyramidal Complex Connected by Hydrogen Bridges to Polymeric Chains
I. Pantenburg, C. Thösen, B. Hoge, Z. Anorg. Allg. Chem., 628 (2002) 1785–1788.
DOI: 10.1002/1521-3749(200208)628:8<1785::AID-ZAAC1785>3.0.CO;2-A
The Bis(trifluoromethyl)phosphanide Anion and Novel Bis(trifluoromethyl)phosphanido Complexes
B. Hoge, C. Thösen, P. Panne, T. Herrmann, I. Pantenburg, Phosphorus, Sulfur, Silicon Relat. Elem., 177 (2002) 1457–1462.
DOI: 10.1080/10426500212240
Stabilization of the P(CF3)2− Ion as a Reversible CS2 Adduct, [P(CF3)2CS2]−, and Its Potential Use as a Nucleophilic P(CF3)2− Source. Synthesis and Structure of [18-Crown-6-K] [P(C6F5)2CS2]
B. Hoge, C. Thösen, T. Herrmann, I. Pantenburg, Inorg. Chem., 41 (2002) 2260–2265.
DOI: 10.1021/ic0112950
Cyanide Initiated Perfluoroorganylations with Perfluoroorgano Silicon Compounds
P. Panne, D. Naumann, B. Hoge, J. Fluorine Chem., 112 (2001) 283–286.
DOI:10.1016/S0022-1139(01)00513-9
Preparation and Characterization of Bis(trifluoromethyl)phosphanide Salts of Outstanding Stability
B. Hoge, C. Thösen, Inorg. Chem., 40 (2001) 3113–3116.
DOI: 10.1021/ic0012064
Synthesis and Properties of Mercury Bis(trifluoromethyl)phosphanides and their Phosphane Complexes
B. Hoge, C. Thösen, I. Pantenburg, Inorg. Chem., 40 (2001) 3084–3088.
DOI: 10.1021/ic001335k
On the Stability of NF4+NO3− and a New Synthesis of Fluorine Nitrate
B. Hoge, K.O. Christe, J. Fluorine Chem., 110 (2001) 87–88.
DOI:10.1016/S0022-1139(01)00415-8
Synthesis and Characterization of the First Examples of Perfluoroalkyl-Substituted Trialkyloxonium Salts, [(CH3)2OCF3]+[Sb2F11]− and [(CH3)2OCF(CF3)2]+[Sb2F11]−
R. Minkwitz, S. Reinemann, R. Seelbinder, D. Konikowski, H. Hartl, I. Grüdgam, J. Hegge, B. Hoge, J.A. Sheehy, K.O. Christe, Inorg. Chem., 40 (2001) 4404–4408.
DOI: 10.1021/ic010239w
Existence of the Halocarbonyl and Trifluoromethyl Cations in the Condensed Phase
K.O. Christe, B. Hoge, J.A. Boatz, G.K.S. Prakasch, G.A. Olah, J.A. Sheehy, Inorg. Chem., 38 (1999) 3132–3142.
DOI: 10.1021/ic990572o
Experimental and Theoretical Characterization of the Oxygen- Coordinated Donor-Acceptor Adducts of COCl2, COClF and COF2 with AsF5 and SbF5 B. Hoge, J.A. Boatz, J. Hegge, K.O. Christe, Inorg. Chem., 38 (1999) 3143–3149.
DOI: 10.1021/ic990157w
A Convenient Synthesis of Carbonyl Chloride Fluoride
B. Hoge, K.O. Christe, J. Fluorine Chem., 94 (1999) 107–108.
DOI:10.1016/S0022-1139(98)00359-5
Trifluoromethylmetallate Anions as Components of Molecular Charge Transfer Salts and Superconductors
J.A. Schlueter, U. Geiser, A.M. Kini, H.H. Wang, J.M. Williams, D. Naumann, T. Roy, B. Hoge, R. Eujen, Coordination Chemistry Reviews, 190–192 (1999) 781–810.
DOI:10.1016/S0010-8545(99)00121-6
Sign Determination of Coupling Constants in CF2H and CF3 Derivatives of Silver(III) Compounds
R. Eujen, B. Hoge, Magn. Reson. Chem., 35 (1997) 707–711.
DOI: 10.1002/(SICI)1097-458X(199711)35:10<707::AID-OMR153>3.0.CO;2-0
Preparation and NMR Spectra of Difluoromethylated Silver(I) and Silver(III) Compounds. The Structure of [PNP][Ag(CF2H)4]
R. Eujen, B. Hoge, D.J. Brauer, Inorg. Chem., 36 (1997) 3160–3166.
DOI: 10.1021/ic961398w
Preparation and NMR Spectra of the Trifluoromethylargentates(III) Ag[(CF3)nX4-n]− with X = CN (n = 1-3), CH3, C6H11, Cl, Br (n =2, 3) and I (n = 3) and of Related Silver(III) Compounds. The Structures of [PPh4][trans-Ag(CF3)2(CN)2] and [PPh4][Ag(CF3)3(CH3)]
R. Eujen, B. Hoge, D.J. Brauer, Inorg. Chem., 36 (1997) 1464–1475.
DOI: 10.1021/ic9610445
Synthesis and Properties of Donor-Free Bis(difluoromethyl)cadmium, (CF2H)2Cd, NMR Spectroscopic Detection and Structure of Tetrakis(difluoromethyl) cuprate(III) and Related Compounds
R. Eujen, B. Hoge, D.J. Brauer, J. Organomet. Chem., 519 (1996) 7–20.
DOI:10.1016/S0022-328X(96)06142-6
Donor-Free Bis(trifluoromethyl)cadmium, (CF3)2Cd: a Readily Available Low-Temperature Difluorocarbene Source
R. Eujen, B. Hoge, J. Organomet. Chem., 503 (1995) C51–C54.
DOI:10.1016/0022-328X(95)05848-J
K. Tölke, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. (2024) e202403226.
DOI: 10.1002/chem.202403226
Halogen Bonding in N-Alkyl-bromo-/iodo-pyridinium Salts and its Application in Chromatography
P. Wendt, J. Bader, P. L. Waltersmann, J.-H. Schröder, M. Keßler, H.-G Stammler, B. Neumann, A. Delp, F. Paesler, M. Schulte, B. Hoge, Chem. Eur. J. (2024) e202403062.
DOI: 10.1002/chem.202403062
First Main-Group Element Lewis Acid Thionyl Chloride Adduct and its Chemistry
K. Tölke, S. Porath, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. (2024) e202408741; Angew. Chem. Int. Ed. (2024) e202408741.
DOI: 10.1002/ange.202408741; DOI: 10.1002/anie.202408741 (Int. Ed.)
Water-Stable Lewis Superacids as Precursors for (Pseudo)halogenogallate and -indate Salts
K. Tölke, S. Porath, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. (2024) e202400191.
DOI: 10.1002/ejic.202400191
Water Adducts of the Lewis Superacids: Tris(pentafluoroethyl)gallane and -indane
K. Tölke, S. Porath, Y. V. Vishnevskiy, B. Neumann, H.-G. Stammler, N. W. Mitzel, B. Hoge, Eur. J. Inorg. Chem. 27, (2024) e202300759.
DOI: 10.1002/ejic.202300759
Gallate and Indate Salts with Unsaturated Electron Withdrawing Groups
S. Porath, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. 27, (2024) e202300642.
DOI: 10.1002/ejic.202300642
Ice nucleation in aqueous solutions of short- and long-chain poly(vinyl alcohol) studied with a droplet microfluidics setup
L. Eickhoff, M. Keßler, C. Stubbs, J. Derksen, M. Viefhues, D. Anselmetti, M. I. Gibson, B. Hoge, T. Koop, J. Chem. Phys. 158, (2023) 154504.
DOI: 10.1063/5.0136192
Triorganylphosphoranides: Realization of an Unusual Structural Motif Utilizing Electron Withdrawing Pentafluoroethyl Groups
M. Keßler, M. Kapiza, H.-G. Stammler, B. Neumann, G.-V. Röschenthaler, B. Hoge, ChemPlusChem 88, (2023) e202200436.
DOI: 10.1002/cplu.202200436
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Synthesis and Characterization of Tetrakis(pentafluoroethyl)indate Salts
S. Porath, M. Keßler, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 29, (2023) e202203278.
DOI: 10.1002/chem.202203278
Synthesis and characterization of tetrafluorophenyl phosphonic acid functionalized polyacrylates as potential proton conducting materials in fuel cells
C. Alter, R. F. Weitkamp, B. Hoge, J. Appl. Polym. Sci. 140(3) (2022) e53313.
DOI: 10.1002/app.53313
Free Difluorobis(pentafluoroethyl)phosphoranide Ion and Its Ligand Properties
M. Keßler, L. Hartmann, H.-G. Stammler, B. Neumann, G.-V. Röschenthaler, B. Hoge, Inorg. Chem. 61 (2022) 10833–10843.
DOI: 10.1021/acs.inorgchem.2c01143
News in ChemistryViews: + Hot Paper
Synthesis, Reactivity and Structural Properties of Trifluoromethylphosphoranides
O. O. Shyshkov, A. A. Kolomeitsev, B. Hoge, E. Lork, A. Haupt, M. Keßler, G.-V. Röschenthaler, Chem. Eur. J. 28 (2022) e202104308.
DOI: 10.1002/chem.202104308
Hot Paper + Frontispiece:
Oxidative Additions of C−F Bonds to the Silanide Anion [Si(C2F5)3]−
N. Tiessen, M. Keßler, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 134 (2022) e202116468; Angew. Chem. Int. Ed. 61 (2022) e202116468.
DOI: 10.1002/ange.202116468;DOI: 10.1002/anie.202116468 (Int. Ed.); Frontispiece
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Difluorobis(pentafluoroethyl)phosphoranide: A Promising Building Block for Phosphoranidometal Complexes
M. Keßler, H.-G. Stammler, B. Neumann, G.-V. Röschenthaler, B. Hoge, Inorg. Chem. 60 (2021) 16466–16473.
DOI: 10.1021/acs.inorgchem.1c02307
Salts of Tris(pentafluoroethyl)silylchalcogenolates [Si(C2F5)3E]− with E = S, Se, and Te: Synthesis, Structure, and Reactivity
N. Tiessen, N. Schwarze, H.-G. Stammler, B. Neumann, B. Hoge, Inorg. Chem. 60 (2021) 15112–15117.
DOI: 10.1021/acs.inorgchem.1c02476
Cover Feature:
Tris(pentafluoroethyl)silanol Derivatives and the Lewis Amphoteric Tris(pentafluoroethyl)silanolate Anion, [Si(C2F5)3O]−
N. Tiessen, N. Schwarze, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 27 (2021) 11041–11044.
DOI: 10.1002/chem.202101845
Frontispiece:
Phosphorus-containing Superbases: Recent Progress in the Chemistry of Electron-abundant Phosphines and Phosphazenes
R. F. Weitkamp, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 27 (2021) 10807–10825.
DOI: 10.1002/chem.202101065; Frontispiece
Frontispiece:
The Influence of Weakly Coordinating Cations on the O−H⋅⋅⋅O− Hydrogen Bond of Silanol‐Silanolate Anions
R. F. Weitkamp, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 27 (2021) 915–920.
DOI: 10.1002/chem.202004236; Frontispiece
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Structural Characterization of Hydro-, Chloro- and Fluoroorganylsilanes with Substituents of Varying Electron Withdrawing Character
M. Keßler, S. Porath, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. (2021) 907–913.
DOI: 10.1002/ejic.202001065; Cover
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Nachweis des Lewis-amphoteren Charakters von Tris(pentafluorethyl)silanid, [Si(C2F5)3]−
N. Tiessen, M. Keßler, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 133 (2021) 12231–12238; Angew. Chem. Int. Ed. 60 (2021) 12124–12131.
DOI: 10.1002/ange.202016455; DOI: 10.1002/anie.202016455 (Int. Ed.); Front Cover
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Non-coordinated and Hydrogen Bonded Phenolate Anions as One-Electron Reducing Agents
R. F. Weitkamp, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 27 (2021) 6465–6478.
DOI: 10.1002/chem.202005123; Cover
Cover Feature:
Ishikawa’s Reagent – a Valuable Source for Fluoroorganic Iminium Salts
M. Keßler, B. Neumann, H.-G. Stammler, B. Hoge, Z. Anorg. Allg. Chem. 647 (2021) 225–230.
DOI: 10.1002/zaac.202000198; Cover
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Non-Coordinated Phenolate Anions and Their Application in SF6 Activation
R. F. Weitkamp, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 27 (2021) 6460–6464.
DOI: 10.1002/chem.202003504; Cover
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Synthesis and Characterization of Tetrakis(pentafluoroethyl)aluminate
N. Tiessen, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 26 (2020) 13611–13614.
DOI: 10.1002/chem.202000668; Back Cover
Autoren-Profil:
Unter Druck entstehen Diamanten (Berthold Hoge)
B. Hoge, Angew. Chem. 132 (2020) 20924; Angew. Chem. Int. Ed. 59 (2020), 20740.
DOI: 10.1002/ange.202008186; DOI: 10.1002/anie.202008186 (Int. Ed.)
Fluorotrimethyl[(Z)-pentafluoropropen-1-yl]phosphorane: Structure, Bonding, and Reactivity
M. Keßler, B. Neumann, H.-G. Stammler, B. Hoge, Z. Anorg. Allg. Chem. 646 (2020) 784–789.
DOI: 10.1002/zaac.202000047
Synthese und Reaktivität der ersten isolierten wasserstoffverbrückten Silanol-Silanolat-Anionen
R. Weitkamp, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 132 (2020) 5536–5541; Angew. Chem. Int. Ed. 59 (2020) 5494–5499.
DOI: 10.1002/ange.201914339; DOI: 10.1002/anie.201914339 (Int. Ed.)
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Generierung und Anwendung des Hydroxid-Trihydrat-Anions, [OH(OH2)3]−, stabilisiert durch ein schwach koordinierendes Kation
R. Weitkamp, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 131 (2019) 14775–14780; Angew. Chem. Int. Ed. 58 (2019) 14633–14638.
DOI: 10.1002/ange.201908589; DOI: 10.1002/anie.201908589 (Int. Ed.); Back Cover
Phosphido-Bridged Di- and Trinuclear Palladium Complexes from Electron-Poor Phosphanes R2PH (R = C2F5, C6F5, (CF3)2C6H3)
J. Bader, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. (2019) 3904–3912.
DOI: 10.1002/ejic.201900728
Cover Image:
Synthesis and characterization of a novel highly phosphonated water-insoluble polymer
C. Alter, B. Neumann, H.-G. Stammler, B. Hoge, J. Appl. Polym. Sci. (2019) 48235.
DOI: 10.1002/app.48235; Cover
VIP + Cover + Cover Profile:
Synthesis and Reactivity of Tris(pentafluoroethyl)gallium Compounds
M. Niemann, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. (2019) 3462–3475.
DOI: 10.1002/ejic.201900486; Cover; Cover Profile
Synthese, Eigenschaften und Anwendung von Tetrakis(pentafluorethyl)gallat, [Ga(C2F5)4]−
M. Niemann, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 131 (2019) 9033–9038; Angew. Chem. Int. Ed. 58 (2019) 8938–8942.
DOI: 10.1002/ange.201904197; DOI: 10.1002/anie.201904197 (Int. Ed.)
Synthesis and characterization of a novel difluoromethylene phosphonic acid functionalized polymer
C. Alter, B. Hoge, J. Appl. Polym. Sci. 135 (2018) 46765.
DOI: 10.1002/app.46765
Coordination Chemistry of the Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2F5)3]−
J. Klösener, M. Wiesemann, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. (2018) 3971–3977.
DOI: 10.1002/ejic.201800796
Hypercoordinated Fluoro(pentafluoroethyl)stannanes and -stannates
J. Klösener, M. Wiesemann, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. (2018) 3960–3970.
DOI: 10.1002/ejic.201800795
Reviews Showcase:
Pentafluoroethylated Compounds of Silicon, Germanium and Tin
M. Wiesemann, B. Hoge, Chem. Eur. J. 24 (2018) 16457–16471.
DOI: 10.1002/chem.201801292
Hot Paper + Cover Feature:
Activation of CH3CN with (C2F5)3PF2 and amines
J. Bader, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 24 (2018) 6975–6982.
DOI: 10.1002/chem.201800682; Inside Cover
Hot Paper:
Synthesis and Reactivity of Donor-Stabilized Bis(pentafluoroethyl)stannylene [Sn(C2F5)2(D)n] (D=THF, DMAP, PMe3, [Sn(C2F5)3]−)
J. Klösener, M. Wiesemann, M. Niemann, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 24 (2018) 4412–4422.
DOI: 10.1002/chem.201705770
The Dynamic Equilibrium of Hexakis(pentafluoroethyl)distannane Adducts [XSn(C2F5)3{Sn(C2F5)3}]− (X=Cl, Br, I, Sn(C2F5)3)
M. Wiesemann, J. Klösener, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 24 (2018) 4336–4342.
DOI: 10.1002/chem.201705069
VIP:
Syntheses of stable salts containing the hydridophosphate anion [P(C2F5)3F2H]−
J. Bader, N. Ignat'ev, B. Hoge, Eur. J. Inorg. Chem. 2018 (2018) 861–866.
DOI: 10.1002/ejic.201701375
Bis(diethylamino)pentafluorophenylphosphane as Valuable Precursor for the Design of Tetrafluorophenylphosphanes, Tetrafluorophenylphosphinic and -phosphonic Acids
C. Alter, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. 2018 (2018) 867–875.
DOI: 10.1002/ejic.201701402
Tris(pentafluoroethyl)stannane: Tin Hydride Chemistry with an Electron-Deficient Stannane
M. Wiesemann, M. Niemann, J. Klösener, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 24 (2018) 2699–2708.
DOI: 10.1002/chem.201705068
Metal-free dehydrogenation of tri- and diethylamine with (C2F5)3PF2
J. Bader, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, J. Fluorine Chem. 207 (2018) 12–17.
DOI: 10.1016/j.jfluchem.2017.12.015
Hot Paper + Cover Feature:
On Pentakis(pentafluoroethyl)stannate, [Sn(C2F5)5]−, and the Gas-Free Generation of Pentafluoroethyllithium, LiC2F5
M. Wiesemann, J. Klösener, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 24 (2018) 1838–1843.
DOI: 10.1002/chem.201704807; Inside Cover
Hot Paper + Cover Feature:
The Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2F5)3]− – Synthesis and Reactivity
M. Wiesemann, J. Klösener, M. Niemann, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 23 (2017) 14476–14484.
DOI: 10.1002/chem.201702855; Inside Cover
VIP + Front Cover + Cover Profile:
Solid-State Structure of a Bromo(difluoromethylenephosphonato)cuprate - a Key Intermediate for the Synthesis of α,α-Difluoromethylenephosphonates
C. Alter, B. Neumann, H.-G. Stammler, L. Weber, B. Hoge, Eur. J. Inorg. Chem. 2017 (2017) 3489–3493.
DOI: 10.1002/ejic.201700526; Cover; Cover Profile
Perfluoroalkylated Main-Group Element Lewis Acids as Catalysts in Transfer Hydrogenation
J. Bader, A. F. G. Maier, J. Paradies, B. Hoge, Eur. J. Inorg. Chem. 2017 (2017) 3053–3056.
DOI: 10.1002/ejic.201700524
Synthesis of Mono-, Bis- and Tris(pentafluoroethyl)tin Derivatives, (C2F5)4–nSnXn (X=Ph, Me, Cl, Br, Cp; n = 1–3)
J. Klösener, M. Wiesemann, M. Niemann, B. Neumann, H.-G. Stammler, B. Hoge, Chem. Eur. J. 23 (2017) 8295–8303.
DOI: 10.1002/chem.201701270
Feature:
Synthesis and Characterization of Tetrakis(pentafluoroethyl)germane
S. Pelzer, B. Neumann, H.-G. Stammler, N. Ignat'ev, R. Eujen, B. Hoge, Synthesis 49 (2017) 2389–2393.
DOI: 10.1055/s-0036-1589005
Hot Paper:
Tris(pentafluoroethyl)germane: Deprotonation and Hydrogermylation Reactions
S. Pelzer, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 23 (2017) 12233–12242.
DOI: 10.1002/chem.201700634
Hot Paper + Back Cover:
Pentafluoroethyl Bismuth Compounds
S. Solyntjes, J. Bader, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 23 (2017) 1557–1567.
DOI: 10.1002/chem.201604910; Back Cover
Bismuth Perfluoroalkylphosphinates: New Catalysts for Application in Organic Syntheses
S. Solyntjes, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 23 (2017) 1568–1575.
DOI: 10.1002/chem.201604914
VIP + Inside Back Cover:
Das Tris(pentafluorethyl)silanid-Anion
N. Schwarze, S. Steinhauer, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 128 (2016) 16390–16394; Angew. Chem. Int. Ed. 55 (2016) 16156–16160.
DOI: 10.1002/ange.201609096; DOI: 10.1002/anie.201609096 (Int. Ed.); Cover
Nukleophile Übertragungsreaktionen der [Si(C2F5)3]−-Einheit
N. Schwarze, S. Steinhauer, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 128 (2016) 16395–16398; Angew. Chem. Int. Ed. 55 (2016) 16161–16164.
DOI: 10.1002/ange.201609575; DOI: 10.1002/anie.201609575 (Int. Ed.)
Pentafluorethylkieselsäuren
N. Schwarze, S. Steinhauer, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem. 128 (2016) 15756–15759; Angew. Chem. Int. Ed. 55 (2016) 15528–15530.
DOI: 10.1002/ange.201609097; DOI: 10.1002/anie.201609097 (Int. Ed.)
Synthesis of Functional Bis(pentafluoroethyl)silanes (C2F5)2SiX2,
with X = H, F, Cl, Br, OPh, O2CCF3
N. Schwarze, B. Kurscheid, S. Steinhauer, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 22 (2016) 17460–17467.
DOI: 10.1002/chem.201603442
Hot Paper:
Hypervalent Pentafluoroethylgermanium Compounds, [(C2F5)nGeX5–n]− and [(C2F5)3GeF3]2- (X = F, Cl; n = 2–5)
S. Pelzer, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 22 (2016) 16460–16466.
DOI: 10.1002/chem.201602859
Cover + Cover Profile:
Novel Difluorotriorganylphosphoranes for the Synthesis of Fluorophosphonium and Bismuthonium salts
S. Solyntjes, B. Neumann, H.-G. Stammler, N. Ignatiev, B. Hoge, Eur. J. Inorg. Chem. (2016) 3999–4010.
DOI: 10.1002/ejic.201600539; Cover; Cover Profile
Das Bis(pentafluorethyl)germylen-Trimethylphosphan-Addukt, (C2F5)2Ge·PMe3 – Charakterisierung, Ligandeigenschaften und Reaktivität
S. Pelzer, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Angew. Chem. 128 (2016) 6192–6197; Angew. Chem. Int. Ed. 55 (2016) 6088–6092.
DOI: 10.1002/ange.201601468; DOI: 10.1002/anie.201601468 (Int. Ed.)
Hot Paper:
Synthesis of Bis(pentafluoroethyl)germanes
S. Pelzer, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 22 (2016) 4758–4763.
DOI: 10.1002/chem.201505084
Hot Paper + Inside Back Cover:
Synthesis of Tris(pentafluoroethyl)germanes
S. Pelzer, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 22 (2016) 3327–3332.
DOI: 10.1002/chem.201504626; Inside Back Cover
Hot Paper:
Coordination Properties of Perfluoroethyl- and Perfluorophenyl-Substituted Phosphonous acids, RfP(OH)2
N. Allefeld, B. Kurscheid, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 21 (2015) 13666–13675.
DOI: 10.1002/chem.201501984
Transition Metal Complexes of Phosphinous Acids Featuring a Quasichelating Unit: Synthesis, Characterization, and Hetero-bimetallic Complexes
N. Allefeld, J. Bader, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Inorg. Chem. 54 (2015) 7945–7952.
DOI: 10.1021/acs.inorgchem.5b01038
Hot Paper + Inside Cover:
Functionalized Pentafluoroethylphosphanes
N. Allefeld, B. Neumann, H.-G. Stammler, N. Ignat'ev, B. Hoge, Chem. Eur. J. 21 (2015) 12326–12336.
DOI: 10.1002/chem.201501733; Inside Cover
Correction: Pentafluoroethyl-substituted α-Silanes: Model Compounds for New Insights
B. Waerder, S. Steinhauer, C. G. Reuter, J. Bader, B. Neumann, H.-G. Stammler, Y. V. Vishnevskiy, B. Hoge, N. W. Mitzel, Dalton Trans. 44 (2015) 14540.
DOI: 10.1039/C5DT90132D
Pentafluoroethyl-substituted α-Silanes: Model Compounds for New Insights
B. Waerder, S. Steinhauer, J. Bader, B. Neumann, H.-G. Stammler, Y. V. Vishnevskiy, B. Hoge, N. W. Mitzel, Dalton Trans. 44 (2015) 13347–13358.
DOI: 10.1039/C5DT02010G
Recent Progress in Perfluoroalkyl-Phosphorus Chemistry
N. V. Ignat'ev, J. Bader, K. Koppe, B. Hoge, H. Willner, J. Fluorine Chem., 171 (2015) 36–45.
DOI: 10.1016/j.jfluchem.2014.10.007
NHC→SiCl4: An Ambivalent Carbene Transfer Reagent
T. Böttcher, S. Steinhauer, L. C. Lewis-Alleyne, B. Neumann, H.-G. Stammler, B. S. Bassil, G.-V. Röschenthaler, B. Hoge, Chem. Eur. J., 21 (2015) 893–899.
DOI: 10.1002/chem.201404628
Festkörperstruktur eines Li⁄F-Carbenoids: Pentafluorethyllithium
B. Waerder, S. Steinhauer, B. Neumann, H.-G. Stammler, A. Mix, Y. V. Vishnevskiy, B. Hoge, N. W. Mitzel, Angew. Chem., 126 (2014), 11824–11828; Angew. Chem. Int. Ed., 53 (2014) 11640–11644.
DOI: 10.1002/ange.201406564; DOI: 10.1002/anie.201406564 (Int. Ed.)
Synthese von Chlorosilikaten
S. Steinhauer, T. Böttcher, N. Schwarze, B. Neumann, H.-G. Stammler, B. Hoge, Angew. Chem., 126 (2014), 13485–13488; Angew. Chem. Int. Ed., 53 (2014), 13269–13272.
DOI: 10.1002/ange.201406311; DOI: 10.1002/anie.201406311 (Int. Ed.)
Synthesis of Functional Phosphates [P(C2F5)3F2X]− from the Phosphorane Adduct [P(C2F5)3F2(dmap)]
J. Bader, N. Ignat'ev, B. Hoge, Inorg. Chem., 53 (2014) 7547–7553.
DOI: 10.1021/ic500857b
Cover + Cover Profile:
Synthesis of Unsymmetrically Substituted Phosphane Oxides (R1R2P(O)H) and Phosphinous Acids (R1R2POH)
N. Allefeld, M. Grasse, N. Ignat'ev, B. Hoge, Chem. Eur. J., 20 (2014) 8615–8620.
DOI: 10.1002/chem.201402425; Cover; Cover Profile
Inside Back Cover:
Pentacoordinate silicon(IV): cationic, anionic and neutral complexes derived from the reaction of NHC→SiCl4 with highly Lewis acidic (C2F5)2SiH2
T. Böttcher, S. Steinhauer, B. Neumann, H.-G. Stammler, G.-V. Röschenthaler, B. Hoge, Chem. Commun., 50 (2014) 6204–6206.
DOI: 10.1039/C4CC02583K; Inside Back Cover
Back Cover:
Synthesis and Reactivity of New Functionalized Perfluoroalkylfluorophosphates
N. Allefeld, B. Neumann, H.-G. Stammler, G.-V. Röschenthaler, N. Ignat'ev, B Hoge, Chem. Eur. J., 20 (2014) 7736–7745.
DOI: 10.1002/chem.201402421; Back Cover
VIP:
Synthese von Tris- und Tetrakis(pentafluorethyl)silanen
S. Steinhauer, J. Bader, H.-G. Stammler, N. Ignat'ev, B. Hoge, Angew. Chem., 126 (2014) 5307–5310; Angew. Chem. Int. Ed., 53 (2014) 5206–5209.
DOI: 10.1002/ange.201400291; DOI: 10.1002/anie.201400291 (Int. Ed.)
Carbene complexes of phosphorus(V) fluorides substituted with perfluoroalkyl-groups synthesized by oxidative addition. Cleavage of the complexes reveals a new synthetic protocol for ionic liquids
T. Böttcher, S. Steinhauer, N. Allefeld, B. Hoge, B. Neumann, H.-G. Stammler, B. S. Bassil, M. Winter, N. W. Mitzel, G.-V. Röschenthaler, Dalton Trans., 43 (2014), 2979–2987.
DOI: 10.1039/C3DT53043D
Synthesis of Five- and Six-coordinated Tris(pentafluoroethyl)fluorosilicates
S. Steinhauer, B. Hoge, B. Neumann, H.-G. Stammler, N. Ignat'ev, Angew. Chem., 126 (2014), 573–575; Angew. Chem. Int. Ed., 53 (2014), 562–564.
DOI: 10.1002/ange.201308059; DOI: 10.1002/anie.201308059 (Int. Ed.)
Functionalized Bis(pentafluoroethyl)phosphanes: Improved Syntheses and Molecular Structures in the Gas Phase
A. V. Zakharov, Y. V. Vishnevskiy, N. Allefeld, J. Bader, B. Kurscheid, S. Steinhauer, B. Hoge, B. Neumann, H.-G. Stammler, R. J. F. Berger, N. W. Mitzel, Eur. J. Inorg. Chem. (2013) 3392–3404.
DOI: 10.1002/ejic.201300364
Synthesis of a water stable 2,4-bis(trifluoromethyl)phenyl substituted phosphonous acid palladium complex and its catalytic activity in cross-coupling reactions
B. Kurscheid, H.-G. Stammler, B. Neumann, B. Hoge, Z. Anorg. Allg. Chem., 638 (2012) 534–542.
DOI: 10.1002/zaac.201100344
Air stable and catalytically active phosphinous acid transition metal complexes
B. Kurscheid, L. Belkoura, B. Hoge, Organometallics, 31 (2012) 1329–1334.
DOI: 10.1021/om200697u
Investigations of the tautomeric equilibria between phosphane oxides and their corresponding phosphinous acids bearing electron-withdrawing perfluoroaryl groups
B. Kurscheid, W. Wiebe, B. Neumann, H.-G. Stammler, B. Hoge, Eur. J. Inorg. Chem. (2011) 5523–5529.
DOI: 10.1002/ejic.201100984
Air stable platinum and palladium complexes featuring bis[2,4-bis(trifluoromethyl)-phenyl]phosphinous acid ligands
B. Kurscheid, H.-G. Stammler, B. Neumann, B. Hoge, Chem. Eur. J., 17 (2011) 14935–14941.
DOI: 10.1002/chem.201102347
First Solid State Structures of Real Diorganyl Phosphinous Acids R2POH (R = CF3, C2F5)
J. Bader, R. J. F. Berger, H.-G. Stammler, N. W. Mitzel, B. Hoge, Chem. Eur. J., 17 (2011) 13420–13423.
DOI: 10.1002/chem.201102370
Chlorobis(pentafluoroethyl)phosphane: Improved Synthesis and Molecular Structure in the Gas Phase
S. A. Hayes, R. J. F. Berger, N. W. Mitzel, J. Bader, B. Hoge, Chem. Eur. J., 17 (2011) 3968–3976.
DOI: 10.1002/chem.201003048
Molecular structure of tris(pentafluoroethyl)phosphane P(C2F5)3
S. A. Hayes, R. J. F. Berger, B. Neumann, N. W. Mitzel, J. Bader, B. Hoge, Dalton Trans., 39 (2010) 5630–5636.
DOI: 10.1039/c001310b
On the XeF+/H2O System: Synthesis and Characterization of the Xenon(II) Oxide Fluoride Cation, FXeOXeFXeF+
M. Gerken, M. D. Moran, H. P. A. Mercier, B. E. Pointner, G. J. Schrobilgen, B. Hoge, K. O. Christe, J. A. Boatz, J. Am. Chem. Soc., 131 (2009) 13474–13489.
DOI: 10.1021/ja905060v
Fluorinated Dithieno[3,2-b:2’,3’-d]phospholes with Highly Stabilized LUMO Levels
Y. Ren, Y. Dienes, S. Hettel, M. Parvez, B. Hoge, T. Baumgartner, Organometallics, 28 (2009) 734–740.
DOI: 10.1021/om800874d
The Bis(pentafluoroethyl)phosphinous Acid, (C2F5)2POH
B. Hoge, J. Bader, H. Beckers, Y. S. Kim, R. Eujen, H. Willner, N. Ignatiev, Chem. Eur. J., 15 (2009) 3567–3576.
DOI: 10.1002/chem.200801837
The influence of electron withdrawing groups on the chemistry of phosphorus: Tautomerization of novel bis(s-triazinyl)phosphanes
B. Hoge, W. Wiebe, Angew. Chem., 120 (2008) 8236–8239; Angew. Chem. Int. Ed., 47 (2008) 8116–8119.
DOI: 10.1002/ange.200802943; DOI: 10.1002/anie.200802943 (Int. Ed.)
Tetrakis[2,4-bis(trifluoromethyl)phenyl]diphosphoxane - An Anhydride of a Phosphinous Acid
B. Hoge, B. Kurscheid, Angew. Chem., 120 (2008) 6920–6922; Angew. Chem. Int. Ed., 47 (2008) 6814–6816.
DOI: 10.1002/ange.200801025; DOI: 10.1002/anie.200801025 (Int. Ed.)
Convenient Access to Trifluoromethanol
K.O. Christe, J. Hegge, B. Hoge, R. Haiges, Angew. Chem., 119 (2007) 6267–6270; Angew. Chem. Int. Ed., 46 (2007) 6155–6158.
DOI: 10.1002/ange.200701823; DOI: 10.1002/anie.200701823
A Convenient, Selective Synthesis of Bis[2,4-bis(trifluoromethyl)phenyl]phosphane Derivatives Starting from 1,3-Bis(trifluoromethyl)benzene
B. Hoge, B. Kurscheid, S. Peuker, W. Tyrra, H. T. M. Fischer, Z. Anorg. Allg. Chem., 633 (2007) 1679–1685.
DOI: 10.1002/zaac.200700140
A Qualitative Scale for the Electron Withdrawing Effect of Substituted Phenyl Groups and Heterocycles
B. Hoge, J. Bader, J. Fluorine Chem., 128 (2007) 857–861.
DOI:10.1016/j.jfluchem.2007.04.007
Synthesis of a Functional C2 Symmetrical Bidentate Diphenylphosphonite DIOP Derivative and its Conversion into the Corresponding π Acidic Bis(pentafluorophenyl) and Bis(p-tetrafluoropyridyl) Derivatives
B. Hoge, P. Panne, Chem. Eur. J., 12 (2006) 9025–9035.
DOI: 10.1002/chem.200600260
Synthesis of the First Chiral Bidentate Bis(trifluoromethyl)phosphane Ligand via the Stabilization of the Bis(trifluoromethyl)phosphanide Anion in the Presence of Acetone
B. Hoge, C. Thösen, Chem. Eur. J., 12 (2006) 9019–9024.
DOI: 10.1002/chem.200600259
Conference Report: Transatlantic Frontiers of Chemistry
A. Herrmann, B. Hoge, W. Maison, Nachr. Chem., 54 (2006) 1258–1260.
The Bis(trifluoromethyl)phosphinous Acid, (CF3)2P-O-H: An Example of a Thermally Stable Phosphinous Acid-Synthesis, Gas-Phase Structure and Rotational Isomers
B. Hoge, P. Garcia, H. Willner, H. Oberhammer, Chem. Eur. J., 12 (2006) 3567–3574.
DOI: 10.1002/chem.200501066
Silver compounds in synthetic chemistry Part 4. 4-Tetrafluoropyridyl silver(I), AgC5F4N in redox transmetallations-possibilities and limitations in reactions with group 15 elements
W. Tyrra, S. Aboulkacem, B. Hoge, W. Wiebe, I. Pantenburg, J. Fluorine Chem., 127 (2006) 213–217.
DOI:10.1016/j.jfluchem.2005.10.009
How Trimethyl(trifluoromethyl)silane Reacts with Itself in the Presence of Naked Fluoride - A One-Pot Synthesis of Bis([15]crown-5)cesium 1,1,1,3,5,5,5-Heptafluoro-2,4-bis(trifluoromethyl)pentenide
W. Tyrra, M. M. Kremlev, D. Naumann, H. Scherer, H. Schmidt, B. Hoge, I. Pantenburg, Y. L. Yagupolskii, Chem. Eur. J., 11 (2005) 6514–6518.
DOI: 10.1002/chem.200500799
Trendbericht 2004, Anorganische Chemie, Hauptgruppenelemente
H.-J. Himmel, B. Hoge, Nachr. Chem., 53 (2005) 225–235.
Stable Phosphinous Acids
B. Hoge, W. Wiebe, S. Neufeind, S. Hettel, C. Thösen, J. Organomet. Chem., 690 (2005) 2382–2387.
DOI:10.1016/j.jorganchem.2004.09.041
Strategies for the Synthesis of Chiral, Bidentate Bis(perfluoroorganyl)phosphane Ligands
B. Hoge, C. Thösen, T. Herrmann, P. Panne, I. Pantenburg, J. Fluorine Chem., 125 (2004) 831–851.
DOI:10.1016/j.jfluchem.2004.02.012
Preparation and Characterization of the Argentates: [Ag{P(CF3)2}2]−, [Ag{(μ-P(CF3)2)W(CO)5}2]− and [Ag{(μ-P(C6F5)2)W(CO)5}2]− and the the X-ray Crystal Structure of [K(18-crown-6)][Ag{(μ-P(CF3)2)Cr(CO)5}2]
B. Hoge, T. Herrmann, C. Thösen, A. Vij, Inorg. Chem., 43 (2004) 1659–1666.
DOI: 10.1021/ic034936v
Non-cyclic [10-S-5] Sulfuranide Dioxide Salts with Three S-C Bonds: A New Class of Stable Hypervalent Compounds
D. V. Sevenard, A. A. Kolomeitsev, B. Hoge, E. Lork, G.-V. Röschenthaler, J. Am. Chem. Soc., 125 (2003) 12366–12367.
DOI: 10.1021/ja030155h
Preparation and Characterization of [Hg{P(C6F5)2}2], [Hg{(μ-P(C6F5)2)W(CO)5}2] and [Hg{(μ-P(CF3)2)W(CO)5}2] and the X-ray Crystal Structure of [Hg{(μ-P(C6F5)2)W(CO)5}2]·2 DMF
B. Hoge, T. Herrmann, C. Thösen, I. Pantenburg, Inorg. Chem., 42 (2003) 5422–5428.
DOI: 10.1021/ic034448n
Stabilization of the P(CF3)2- and P(C6F5)2- ion by coordination to pentacarbonyl tungsten.
Structures of [18-crown-6-K]P(CF3)2, [18-crown-6-K][W{P(CF3)2}(CO)5] and [18-crown-6-K] [{W(CO)5}2{μ-P(C6F5)2}]·THF
B. Hoge, C. Thösen, T. Herrmann, I. Pantenburg, Inorg. Chem., 42 (2003) 3633–3641.
DOI: 10.1021/ic034165v
Bis(trifluoromethyl)phosphane, Bis(pentafluorophenyl)phosphane and their Pentacarbonyl Tungsten Complexes: Improved Synthesis and an Experimental and Density Functional Study.
B. Hoge, T. Herrmann, C. Thösen, I. Pantenburg, Inorg. Chem., 42 (2003) 3623–3632.
DOI: 10.1021/ic034166n
Vibrational spectra and structures of fluoroalkyl and fluoroaryl compounds of tellurium: Te2(CF3)2, Te2(C6F5)2 and Te(C6F5)2
B. Hoge, D. Naumann, H. Pohl, J. Shamir, J. Raman Spec., 34 (2003) 33–39.
DOI: 10.1002/jrs.936
A new synthesis of trifluoromethanethiolates - characterization and properties of tetramethylammonium, cesium and di(benzo-15-crown-5)cesium trifluoromethanthiolates
W. Tyrra, D. Naumann, B. Hoge, Y. L. Yagupolskii, J. Fluorine Chem., 119 (2003) 101–107.
DOI:10.1016/S0022-1139(02)00276-2
Novel Addition of Diphosphanes to Carbonyl Compounds
B. Hoge, C. Thösen, Phosphorus, Sulfur, Silicon Relat. Elem., 177 (2002) 2151–2152.
DOI: 10.1080/10426500213437
Synthesis and Structure of [Hg{OP(O)CF3(OH)}2(PMe3)3], a Distorted Trigonal Bipyramidal Complex Connected by Hydrogen Bridges to Polymeric Chains
I. Pantenburg, C. Thösen, B. Hoge, Z. Anorg. Allg. Chem., 628 (2002) 1785–1788.
DOI: 10.1002/1521-3749(200208)628:8<1785::AID-ZAAC1785>3.0.CO;2-A
The Bis(trifluoromethyl)phosphanide Anion and Novel Bis(trifluoromethyl)phosphanido Complexes
B. Hoge, C. Thösen, P. Panne, T. Herrmann, I. Pantenburg, Phosphorus, Sulfur, Silicon Relat. Elem., 177 (2002) 1457–1462.
DOI: 10.1080/10426500212240
Stabilization of the P(CF3)2− Ion as a Reversible CS2 Adduct, [P(CF3)2CS2]−, and Its Potential Use as a Nucleophilic P(CF3)2− Source. Synthesis and Structure of [18-Crown-6-K] [P(C6F5)2CS2]
B. Hoge, C. Thösen, T. Herrmann, I. Pantenburg, Inorg. Chem., 41 (2002) 2260–2265.
DOI: 10.1021/ic0112950
Cyanide Initiated Perfluoroorganylations with Perfluoroorgano Silicon Compounds
P. Panne, D. Naumann, B. Hoge, J. Fluorine Chem., 112 (2001) 283–286.
DOI:10.1016/S0022-1139(01)00513-9
Preparation and Characterization of Bis(trifluoromethyl)phosphanide Salts of Outstanding Stability
B. Hoge, C. Thösen, Inorg. Chem., 40 (2001) 3113–3116.
DOI: 10.1021/ic0012064
Synthesis and Properties of Mercury Bis(trifluoromethyl)phosphanides and their Phosphane Complexes
B. Hoge, C. Thösen, I. Pantenburg, Inorg. Chem., 40 (2001) 3084–3088.
DOI: 10.1021/ic001335k
On the Stability of NF4+NO3− and a New Synthesis of Fluorine Nitrate
B. Hoge, K.O. Christe, J. Fluorine Chem., 110 (2001) 87–88.
DOI:10.1016/S0022-1139(01)00415-8
Synthesis and Characterization of the First Examples of Perfluoroalkyl-Substituted Trialkyloxonium Salts, [(CH3)2OCF3]+[Sb2F11]− and [(CH3)2OCF(CF3)2]+[Sb2F11]−
R. Minkwitz, S. Reinemann, R. Seelbinder, D. Konikowski, H. Hartl, I. Grüdgam, J. Hegge, B. Hoge, J.A. Sheehy, K.O. Christe, Inorg. Chem., 40 (2001) 4404–4408.
DOI: 10.1021/ic010239w
Existence of the Halocarbonyl and Trifluoromethyl Cations in the Condensed Phase
K.O. Christe, B. Hoge, J.A. Boatz, G.K.S. Prakasch, G.A. Olah, J.A. Sheehy, Inorg. Chem., 38 (1999) 3132–3142.
DOI: 10.1021/ic990572o
Experimental and Theoretical Characterization of the Oxygen- Coordinated Donor-Acceptor Adducts of COCl2, COClF and COF2 with AsF5 and SbF5 B. Hoge, J.A. Boatz, J. Hegge, K.O. Christe, Inorg. Chem., 38 (1999) 3143–3149.
DOI: 10.1021/ic990157w
A Convenient Synthesis of Carbonyl Chloride Fluoride
B. Hoge, K.O. Christe, J. Fluorine Chem., 94 (1999) 107–108.
DOI:10.1016/S0022-1139(98)00359-5
Trifluoromethylmetallate Anions as Components of Molecular Charge Transfer Salts and Superconductors
J.A. Schlueter, U. Geiser, A.M. Kini, H.H. Wang, J.M. Williams, D. Naumann, T. Roy, B. Hoge, R. Eujen, Coordination Chemistry Reviews, 190–192 (1999) 781–810.
DOI:10.1016/S0010-8545(99)00121-6
Sign Determination of Coupling Constants in CF2H and CF3 Derivatives of Silver(III) Compounds
R. Eujen, B. Hoge, Magn. Reson. Chem., 35 (1997) 707–711.
DOI: 10.1002/(SICI)1097-458X(199711)35:10<707::AID-OMR153>3.0.CO;2-0
Preparation and NMR Spectra of Difluoromethylated Silver(I) and Silver(III) Compounds. The Structure of [PNP][Ag(CF2H)4]
R. Eujen, B. Hoge, D.J. Brauer, Inorg. Chem., 36 (1997) 3160–3166.
DOI: 10.1021/ic961398w
Preparation and NMR Spectra of the Trifluoromethylargentates(III) Ag[(CF3)nX4-n]− with X = CN (n = 1-3), CH3, C6H11, Cl, Br (n =2, 3) and I (n = 3) and of Related Silver(III) Compounds. The Structures of [PPh4][trans-Ag(CF3)2(CN)2] and [PPh4][Ag(CF3)3(CH3)]
R. Eujen, B. Hoge, D.J. Brauer, Inorg. Chem., 36 (1997) 1464–1475.
DOI: 10.1021/ic9610445
Synthesis and Properties of Donor-Free Bis(difluoromethyl)cadmium, (CF2H)2Cd, NMR Spectroscopic Detection and Structure of Tetrakis(difluoromethyl) cuprate(III) and Related Compounds
R. Eujen, B. Hoge, D.J. Brauer, J. Organomet. Chem., 519 (1996) 7–20.
DOI:10.1016/S0022-328X(96)06142-6
Donor-Free Bis(trifluoromethyl)cadmium, (CF3)2Cd: a Readily Available Low-Temperature Difluorocarbene Source
R. Eujen, B. Hoge, J. Organomet. Chem., 503 (1995) C51–C54.
DOI:10.1016/0022-328X(95)05848-J